Product ID:GLYCOL FR-40 XD, 48-320
MSDS Date:06/02/1986
FSC:9150
NIIN:00N043253
MSDS Number: CCNJP

CITGO PETROLEUM CORP

TULSA, OK 74102
US

Emergency Phone: 318-491-6215

Info Phone: 918-561-5165

Cage: 1JW40

CITIES SERVICE CO

300 TULSA, OK 74102 US

Telephone: 918-561-5165

Cage: 12518

(ORAL,RAT)5.8 G/KG

CAS: 107-21-1

RTECS: KW2975000

Fraction By Weight: 60-80%

OSHA PEL 50 PPM, C

ACGIH TLV: 50 PPM,VAPOR, C

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

WATER

CAS: 7732-18-5

RTECS: ZC0110000

Fraction By Weight: 30-50%

OSHA PEL N/K

ACGIH TLV: N/K

(ORAL,RAT)5G/KG

Fraction By Weight: <0.1%

OSHA PEL N/K

ACGIH TLV: N/K

DYE; (ORGANIC NITROGEN COMPOUND)

Fraction By Weight: <0.1%

OSHA PEL N/K

ACGIH TLV: N/K

LD50 LC50 Mixture:SEE INGREDIENTS
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: LOW HAZ-ANIMAL TOX DATA
INDICATE THAT THIS PROD IS ESSENTIALLY NON TOX FOLLOWING INHAL.
CHRONIC EXPOS TO ETHYLENE GLYCOL PROCESS VAPS MAY PRDCE LUNG IRRIT,
UNCON, &/OR BLOOD ABNORM. SKIN: NOT A PRIMARY SKIN IRRITANT. MAY
CAUSE IRRITUPON RPTD/PRLNGD CONT. POSS IF LG AREAS OF BODY AFFECTED
SYS (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: AS IN INGEST. EYE: MAY BE MILDLY
IRRITATING. THOUGH ANIMAL TOX DATA FOR THIS PROD INDICATES THAT IT
IS A LOW EYE IRRITANCY, EYE CONT SHOULD BE AVOIDED. INGEST:
ALCOHOL-LIKE INTOX PROCESSIN T O VOMIT, WEAK PULSE, DFCLT BRTHG,
PARALYSIS, CONVULS, COMA, KIDNEY DAMAGE. CHRONIC: NONE KNOWN.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INHAL: REMOVE FROM EXPOS. RESP SUPPORT IF NEC. SEEK MED AID.
SKIN: WASH W/SOAP & WATER. SUBCUTANEOUS INJECTION IS A MED EMER.
SEEK MED AID IMMED. LAUNDER WETTED CLTHG. EYES: FLUSH W/WATER FOR @
LST 15 MIN-SEEK MED AID IF COMPLICATIONS ARISE. INGEST:INDUCE
VOMIT. SEEK IMMED MED AID. DO NOT INDUCE VOMIT IF UNCON. NOTES TO
PHYS: IMMED TRTMT IS ESSENTIAL FOR ACCIDENTAL INGEST. PROD CNTNS
(SUPP DATA)

Flash Point:232F,111C
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM/WATER FOG.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE.

Spill Release Procedures:CONTAIN LEAK. ABSORB SMALL SPILLS WITH
SUITABLE MATERIAL SUCH AS STRAW/SAND. REPORT SPILLS AS REQUIRED TO
APPROPRIATE AUTHORITIES. CHEMTREC EMERGENCY #: 800-424-9300.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE BELOW 120F. DO NOT APPLY HIGH
HEAT/FLAME TO CONTAINER. CONTACT W/STRONG OXIDANTS MAY YIELD
FORMALDEHYDE.
Other Precautions:CAUTION: EMPTY CONTAINERS MAY CONTAIN PRODUCT RESIDUE
WHICH COULD INCLUDE FLAMMABLE/EXPLOSIVE VAPORS.

Respiratory Protection:NORMALLY NONE REQUIRED, NIOSH/MSHA APPROVED
ORGANIC VAPOR CARTRIDE ABOVE TLV.
Ventilation:VENTILATION IS REQUIRED WHEN WORK PLACE EXPOSURE EXCEED
TLV.
Protective Gloves:NEOPRENE/BUNA-N.
Eye Protection:ANSI APPROVED CHEM SAFETY GOGGLES
Other Protective Equipment:NONE.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRST AID PROC: ETHYLENE GLYCOL. HUMAN LETHAL DOSE OF CHEM IS REPORTED
TO BE 100 MLS (DANGEROUS PROPERTIES OF INDUST CHEM, 5TH EDITION.
WASTE DISP METH: RECLAIMING, RECYCLING OR DISPOSING OF EMPTY CON
TAINERS AND/OR WASTE RESIDUES OF THIS PRODUCT.

Boiling Pt:B.P. Text:318F,159C
Vapor Pres:<0.05@25C
Vapor Density:>1
Spec Gravity:1.09(H*2O=1)
pH:9-10
Evaporation Rate & Reference:<1(BUTYL ACETATE=1)
Solubility in Water:COMPLETE
Appearance and Odor:RED LIQUID, SLIGHT AMINE ODOR
Percent Volatiles by Volume:NEGLIG

Stability Indicator/Materials to Avoid:YES
STRONG OXIDANTS OR ACIDS, SUCH AS NITRIC OR SULFURIC ACID.
Stability Condition to Avoid:ALKALI AND STRONG OXIDANTS.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE.

Waste Disposal Methods:IT IS THE RESPONSIBILITY OF USER TO DETERM IF
MATL IS A HAZ WASTE @ TIME OF DISP. CHECK BEFORE DISPOSING TO BE
SURE YOU ARE IN COMPLIANCE W/ALL APPLIC LAWS & REGS. CONSULT APPROP
FED, ST & LOC AUTH BE FORE REUSING, RECONDITIONING, (SUPP DATA)

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disclaims all liability for its use. Any person utilizing this
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particular situation.